Reaction Kinetics: Investigation of intermediates and reaction mechanisms.

Publications:

1. High-Pressure Pathway in the Two-Stage Synthesis of 5-Amino-3-Hydroxy-1-Phenyl-1H-Pyrazole.
Grabovskii, S. A.; Andriyashina, N. M.; Lobov, A. N.; Safiullin, R. L.
Letters in Organic Chemistry, 2025, 22(5), 372-378. DOI:
10.2174/0115701786331865241120043030

2. Reactions of 5-(Trialkyl)silylpent-1-en-4-yn-3-ones with Hydrazines: Original Synthetic Routes to Luminescent Substances Containing Azole Motifs.
Golovanov, A. A.; Odin, I. S.; Gordon, K. V.; Itakhunov, R. N.; Gusev, D. M.; Sokov, S. A.; Vologzhanina, A. V.; Grabovskiy, S. A.; Sosnin, I. M.; Ukolov, A. I.; Orlova, O. I.; Lazarenko, V. A.; Dorovatovskii, P. V.; Darmoroz, D. D.; Piven, A. O.; Orlova, T.
Synthesis, 56(02), 243–266. DOI:
10.1055/s-0043-1763601

3. Catalyst-Free Oxidation of Sulfides to Sulfoxides by gem-Dihydroperoxide under Mild Conditions.
Grabovskii, S. A.; Andrijashina, N. M.; Lobov, A. N.; Antipin, A. V.; Safiullin, R. L.
Synlett, 2023, 34(11), 1247–1252. DOI:
10.1055/a-2015-7526

4. Cyclization of arylhydrazones of cross-conjugated enynones: synthesis of luminescent styryl-1H-pyrazoles and propenyl-1H-pyrazoles.
Itakhunov, R. N.; Odin, I. S.; Gusev, D. M.; Grabovskiy, S. A.; Gordon, K. V.; Vologzhanina, A. V.; Sokov, S. A.; Sosnin, I. M.; Golovanov, A. A.
Organic & Biomolecular Chemistry, 2022, 20(44), 8693–8713. DOI:
10.1039/d2ob01427k

5. Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone.
Grabovskiy, S. A.
Russian Journal of General Chemistry, 2022, 92(8), 1443–1448. DOI:
10.1134/S1070363221120069

6. Oxidation of Triorganosilanes and Related Compounds by Chlorine Dioxide.
Grabovskiy, S. A.; Kabal’nova, N. N.
Russian Journal of General Chemistry, 2021, 91(12), 2391–2402. DOI:
10.1134/S1070363222080114

7. Reactivity of Cross-Conjugated Enynones in Cyclocondensations with Hydrazines: Synthesis of Pyrazoles and Pyrazolines.
Golovanov, A. A.; Odin, I.S.; Gusev, D. M.; Vologzhanina, A. V.; Sosnin, I. M.; Grabovskiy, S. A.
The Journal of Organic Chemistry, 2021, 86(10), 7229–7241. DOI:
10.1021/acs.joc.1c00569

8. Reactivity of 5aminouracil derivatives towards peroxyl radicals.
Grabovskii, S. A.; Andriyashina, N. M.; Grabovskaya, Yu. S.; Antipin, A. V.; Kabal’nova, N. N.
Journal of Physical Organic Chemistry, 2020, 33(8), e4065. DOI:
10.1002/poc.4065

9. Synthesis and kinetic regularities of the thermal decomposition of new hydrotrioxides of cyclic alcohols.
Grabovskiy, S.A.; Khalitova, L.R.; Fedorova, A.V.; Lobov, A.N.; Rol'nik, L.Z.; Kabal'nova, N.N.
Russian Chemical Bulletin, 2016, 65(2), 464–468. DOI:
10.1007/s11172-016-1322-2

10. Base-promoted reaction of 5-hydroxyuracil derivatives with peroxyl radicals.
Amorati, R.; Valgimigli, L.; Pedulli, G.F.; Grabovskiy, S.A.; Kabalnova, N.N.; Chatgilialoglu, C.
Organic Letters, 2010, 12(18), 4130–4133. DOI:
10.1021/ol1017245

11. Separation of cis/trans geometrical fatty acid isomers by silver-exchanged zeolite Y.
Ioannis N. Lykakis, Carla Ferreri, Stanislav A. Grabovskiy, Chryssostomos Chatgilialoglu
Tetrahedron, 2010, 66(12), 2203-2209. DOI: 10.1016/j.tet.2010.01.032

12. Oxidation of some cage hydrocarbons by dioxiranes. Nature of the transition structure for the reaction of C-H bonds with dimethyldioxirane: A comparison of B3PW91 density functional theory with experiment.
Grabovskiy, S.A.; Antipin, A.V.; Ivanova, E.V.; Dokichev, V.A.; Tomilov, Y.V.; Kabal'nova, N.N.
Organic & Biomolecular Chemistry, 2007, 5(14), 2302–2310. DOI:
10.1039/b707753j

13. Epoxidation of Polyunsaturated Fatty Acid Double Bonds by Dioxirane Reagent: Regioselectivity and Lipid Supramolecular Organization.
Stanislav A. Grabovskiy, Natalia N. Kabal'nova, Chryssostomos Chatgilialoglu, Carla Ferreri
Helvetica Chimica Acta, 2006, 89(10), 2243-2253.
DOI: 10.1002/hlca.200690209

14. Kinetic and product studies of the reaction of triorganosilanes with dimethyldioxirane.
Grabovskii, S.A.; Kabal'nova, N.N.; Shereshovets, V.V.; Chatgilialoglu, C.
Organometallics, 2002, 21(17), 3506–3510. DOI:
10.1021/om0200095

 


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